Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1309830 | Inorganica Chimica Acta | 2009 | 4 Pages |
Reaction in water between trivalent lanthanide ions and ctc3− ligand leads to [Ln(ctc)(H2O)2 · 2.5H2O]∞ 3-D molecular networks with Ln = Tb–Yb or Y. These compounds look like molecular precursors for porous solids. Unfortunately, the dehydrated phases are not structurally characterized. We report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.
Graphical abstractWe report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.Figure optionsDownload full-size imageDownload as PowerPoint slide