Article ID Journal Published Year Pages File Type
1309830 Inorganica Chimica Acta 2009 4 Pages PDF
Abstract

Reaction in water between trivalent lanthanide ions and ctc3− ligand leads to [Ln(ctc)(H2O)2 · 2.5H2O]∞ 3-D molecular networks with Ln = Tb–Yb or Y. These compounds look like molecular precursors for porous solids. Unfortunately, the dehydrated phases are not structurally characterized. We report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.

Graphical abstractWe report here the study of the partially dehydrated phases with general formula [Ln(ctc)(H2O)2]∞ with Ln = Tb–Yb or Y obtained by freeze-drying of the corresponding hydrated phases. Their porosity is estimated as well as the luminescent properties of the Tb-containing compound.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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