A 2-quinolinecarboxylate-substituted ruthenium(II) complex as a new type of sensitizer for dye-sensitized solar cells

A new type of ruthenium(II) complex containing a 2-quinolinecarboxylate ligand was designed and synthesized as a sensitizer for dye-sensitized solar cells, and its photophysical and photochemical properties were characterized. The solar cells created with this complex exhibited efficient panchromatic sensitization over the entire visible wavelength range extending into the near-IR region. An overall conversion efficiency of 8.2% was attained under standard air mass 1.5 irradiation (100 mW cm−2) with the short-circuit photocurrent density of 18.2 mA cm−2, the open-circuit photovoltage of 0.63 V and the fill factor of 0.72.

Graphical abstractA new type of ruthenium(II) complex containing a 2-quinolinecarboxylate ligand was synthesized as a sensitizer for dye-sensitized solar cells. The solar cell created with this new complex exhibited efficient panchromatic sensitization over the entire visible wavelength range extending into the near-IR region. An overall conversion efficiency of 8.2% was attained under standard air mass 1.5 irradiation (100 mW cm−2).Figure optionsDownload full-size imageDownload as PowerPoint slide