Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1309896 | Inorganica Chimica Acta | 2006 | 6 Pages |
The binuclear manganese (IV) [Mn2(Hsal)4(OH)4] (H2sal = salicylic acid) complex has been obtained from a complex reaction mixture in methanol consisting of Mn(II)(OAc)2 · 4H2O, GS ( a reagent obtained by refluxing glycine and salicylaldehyde in 1:1 molar ratio in methanol), monosodium salicylate and pyridine. The compound contains a distorted octahedral MnO6 coordination unit of potential importance to high oxidation state manganese bimolecules.
Graphical abstractThe binuclear manganese (IV) [Mn2(Hsal)4(OH)4] (Hsal = salicylic acid) complex has been synthesized and characterized by elemental analysis, magnetic moment, EPR, IR and electronic spectral data and X-ray crystallography. The compound contains a distorted octahedral MnO6 coordination unit of potential importance to high oxidation state manganese bimolecules.Figure optionsDownload full-size imageDownload as PowerPoint slide