| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309899 | Inorganica Chimica Acta | 2006 | 6 Pages |
Abstract
Single-crystal X-ray structure of an iron(III) complex of 2-acetyl-1,3-indandione is resolved which reveals that a racemic mixture, composed of Δ-fac and Λ-fac stereoisomers, is formed. Both species have octahedral geometry, but slightly distinguishable. Detailed Mössbauer data indicate a high-spin electronic structure of the Fe(III) centres Fe1 and Fe2 with spin–spin magnetic relaxation process. Two different approaches for computer processing of the experimental Mössbauer spectra are considered.
Graphical abstractView of the unit cell of Fe(2AID)3 complex.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Anife Ahmedova, Ventzislav Rusanov, Alan Hazell, Juliusz A. Wolny, Georgi Gochev, Alfred X. Trautwein, Mariana Mitewa,