| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309921 | Inorganica Chimica Acta | 2006 | 6 Pages |
Abstract
By heating, the hexahalorhenate(IV) anions [ReCl6]2â and [ReBr6]2â undergo a solvolysis reaction in N,N-dimethylformamide (DMF), allowing the isolation of two isostructural compounds of formula NBu4[ReX5(DMF)], being XÂ =Â Cl (1) and Br (2). Magnetic measurements show that these novel octahedral Re(IV) complexes exhibit a large zero-field splitting.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Ligand substitution in hexahalorhenate(IV) complexes: Synthesis, crystal structures and magnetic properties of NBu4[ReX5(DMF)] (XÂ =Â Cl and Br)](/preview/png/1309921.png "First Page Preview: Ligand substitution in hexahalorhenate(IV) complexes: Synthesis, crystal structures and magnetic properties of NBu4[ReX5(DMF)] (XÂ =Â Cl and Br)")
Authors
José Martı´nez-Lillo, Donatella Armentano, Giovanni De Munno, Francesc Lloret, Miguel Julve, Juan Faus,