| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1309931 | Inorganica Chimica Acta | 2006 | 4 Pages |
A 2D grid-like copper(II) complex [Cu(N3)2(pyz)](pyz = pyrazine) (1) has been synthesized and characterized by single crystal X-ray analysis and magnetic measurements. The 2D grid-like network of 1 consists of 1D chain of Cu-pyz units connected by end-on azido bridge. 1 crystallizes in the monoclinic space group C2 with a = 15.148(6) Å, b = 6.877(2) Å, c = 3.4591(12) Å and Z = 2. The magnetic investigation showed the presence of an antiferromagnetic interaction between the copper(II) ions mainly mediated through pyrazine bridge.
Graphical abstractA 2D grid-like copper(II) complex [Cu(N3)2(pyz)](pyz = pyrazine) (1) has been synthesized and characterized by single crystal X-ray analysis and magnetic measurements. The 2D grid-like network of 1 consists of 1D chain of Cu-pyz units connected by end-on azido bridge.Figure optionsDownload full-size imageDownload as PowerPoint slide
