Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1310058 | Inorganica Chimica Acta | 2006 | 8 Pages |
Abstract
Four novel solvated forms are prepared and characterized for diverse silver oxyanion salt:bis(diphenylphosphino)-ligand adducts. AgClO4:dppf:MeCN (2:1:4) ('dppf' = bis(diphenylphosphino)ferrocene) is a binuclear centrosymmetric species. The two MeOH/H2O solvates of AgX:dppp (2:1) are single stranded polymers (X = carboxylate: 'ac' = acetate, 'tfa' = trifluoroacetate; 'dppp' = Ph2P(CH2)xPPh2; x = 3) · MeOH and Agac:dppp:MeOH(2:1:0.5)·312H2O. AgClO4:dppe:MeCN (1:1:1) ('dppe', x = 2), is a one-dimensional polymer with unidentate MeCN and OClO3 coordinated to the silver.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Augusto Cingolani, Effendy Effendy, Claudio Pettinari, Brian W. Skelton, Allan H. White,