| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310063 | Inorganica Chimica Acta | 2006 | 16 Pages |
Abstract
Common product distributions are observed for the capture of water and azide ion during the base catalysed substitution reactions of each of the four meridional isomers of [Co(dien)(ampy)Cl]2+ and [Co(dien)(ibn)Cl]2+. The constant syn/anti and cis/trans ratios pinpoint a common and unique pentacoordinate intermediate as shown.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![The kinetics and stereochemistry of base hydrolysis of the seven isomers of [Co(dien)(ampy)Cl]2+ and [Co(dien)(ibn)Cl]2+](/preview/png/1310063.png "First Page Preview: The kinetics and stereochemistry of base hydrolysis of the seven isomers of [Co(dien)(ampy)Cl]2+ and [Co(dien)(ibn)Cl]2+")
Authors
Tao Zhu, W. Gregory Jackson, David C.R. Hockless, Anthony C. Willis,