| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310125 | Inorganica Chimica Acta | 2008 | 11 Pages |
Abstract
The oxidative addition kinetics, of CH3I to [Rh((C4H3S)COCHCOR)(CO)(PPh3)] with RÂ =Â C6H5 or C4H3S, studied by UV/vis, IR, 1H NMR and 31P NMR techniques consist of three consecutive reaction steps involving isomers of two different RhIII-alkyl and two different RhIII-acyl species.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Methyl iodide oxidative addition to monocarbonylphosphine [Rh((C4H3S)COCHCOR)(CO)(PPh3)] complexes utilizing UV/vis and IR spectrophotometry and NMR spectroscopy to identify reaction intermediates: RÂ =Â C6H5 or C4H3S](/preview/png/1310125.png "First Page Preview: Methyl iodide oxidative addition to monocarbonylphosphine [Rh((C4H3S)COCHCOR)(CO)(PPh3)] complexes utilizing UV/vis and IR spectrophotometry and NMR spectroscopy to identify reaction intermediates: RÂ =Â C6H5 or C4H3S")
Authors
Marrigje M. Conradie, Jeanet Conradie,