| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310169 | Inorganica Chimica Acta | 2006 | 7 Pages |
Abstract
We have prepared and characterized two new bulky amido ligands unexpectedly prepared in an attempt to synthesize [(adamantyl)(2,6-iPr2C6H3)NH]. Rather than reacting at the primary -NH2 functionality, the adamantyl group attacked the 4-position of the 2,6-iPr2C6H3NH2 group to yield substituted ligands. These new ligands afford steric bulk, improved solubility in organic solvents, and an increased tendency to form crystalline compounds.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yongjun Tang, Lev N. Zakharov, Arnold L. Rheingold, Richard A. Kemp,