Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1310257 | Inorganica Chimica Acta | 2008 | 7 Pages |
Abstract
The diiron(II) complex [Fe2(μ-OTf)2(PIC2DET)2](BARF)2, where PIC2DET is a 2,3-diethynyltriptycene-linked dipicolinic methyl ester ligand, has been synthesized and characterized. X-ray crystallographic data reveal a new mode of coordination for the syn N-donor ligand PIC2DET. Molar conductivity, 1H NMR spectroscopic, and magnetic susceptibility data are consistent with a complex containing two high spin iron atoms that retains its structure in solution.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jeremy J. Kodanko, Stephen J. Lippard,