Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1310266 | Inorganica Chimica Acta | 2008 | 13 Pages |
Abstract
The Absolute Configuration (AC) of the chiral chromium complex, tricarbonyl-η6-N-pivaloyl-tetrahydroquinoline-chromium(0) has been determined using Vibrational Circular Dichroism (VCD) spectroscopy. Comparison of the VCD spectrum predicted using the Stephens equation for vibrational rotational strengths, implemented using Density Functional Theory (DFT), to the experimental VCD spectrum shows that the AC is S-(+).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
P.J. Stephens, F.J. Devlin, C. Villani, F. Gasparrini, S. Levi Mortera,