| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310541 | Inorganica Chimica Acta | 2007 | 5 Pages |
Abstract
The five-coordinate hydrido(vinyl) iridium(III) complexes [IrH(Cl){(E)-C(R)CH(CO2Me)}(PiPr3)2] (6, 7) were prepared either from [IrH2(Cl)(PiPr3)2] and RCC(CO2Me), via insertion of the alkyne into one of the IrH bonds or by careful hydrogenation of the alkyne iridium(I) derivatives trans-[IrCl{RCC(CO2Me)}(PiPr3)2]. UV irradiation of 6 (RÂ =Â CO2Me) affords the isomer 3 having the vinyl ligand coordinated in a bidentate fashion.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Thomas Dirnberger, Helmut Werner,