Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1310592 | Inorganica Chimica Acta | 2013 | 6 Pages |
Abstract
⺠The energetically low-lying structures of CX2Fe2(CO)8 (X = H, F) have been characterized by density functional theory. ⺠CH2Fe2(CO)8 has isomers with and without bridging CO groups in equilibrium similar to Co2(CO)8. ⺠A higher energy (CH2CO)Fe2(CO)7 structure is found with a bridging ketene ligand. ⺠Terminal CF2 groups are found in higher energy CF2Fe2(CO)8 structures.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yan Wu, Qiong Luo, Chaoyang Wang, Qian-shu Li, Yaoming Xie, R. Bruce King,