| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310605 | Inorganica Chimica Acta | 2013 | 6 Pages |
Metal(II) acetates of nickel, zinc and cadmium facilitate hydrolysis of 4-(4-oxopentan-2-ylideneamino)benzoic acid (iminocarb). In the case of nickel a dinuclear iminocarb complex is proposed as intermediate species to form nickel complex of 4-aminobenzoic acid (Haben). The nickel complex formed from hydrolysis has a composition [Ni(O2CCH3)2(Haben)2(H2O)2]·2H2O. In this complex, the nitrogen atoms of the 4-aminobenzoic acid ligands coordinate to nickel ion and the benzoic acid end of the ligands remain free. A five coordinate [Zn(aben)2(py)(H2O)] complex is obtained from a similar reaction of iminocarb with zinc(II) acetate followed by reaction with pyridine (py). On the other hand the reaction of iminocarb with cadmium(II) acetate forms a coordination polymer [{Cd(aben)2(H2O)}·H2O]n.
Graphical abstractHydrolysis of 4-(4-oxopentan-2-ylideneamino)benzoic acid is facilitated by various metal acetates such as nickel(II) acetate, zinc(II) acetate and cadmium(II) acetate. The coordination effect in the hydrolysis is presented.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Hydrolysis of 4-(4-oxopentan-2-ylideneamino)benzoic acid is facilitated by metal acetates. ► Coordination effect on formation of different 4-aminobenzoate complexes of Ni, Zn and Cd is discussed. ► A dinuclear intermediate is proposed as reaction intermediate for nickel(II) mediated hydrolysis. ► A five-coordinate zinc(II) 4-aminobenzoate complex is characterized.
