Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1310824 | Inorganica Chimica Acta | 2007 | 6 Pages |
Abstract
In a series of coordination polymers based upon 4,4′-bitriazole (btr) [Cu3Cl2(H2O)2(btr)4]2(ZnCl4)2(Cl3ZnOZnCl3), [Cu3Cl2(H2O)2(btr)4](MCl4)2 (M = Cd; Hg), eight-connected metal-organic frameworks related to a CsCl (bcu) structure originate in the functionality of trinuclear copper/chloride ensembles bridged by the organic ligands. [Cu3Cl4(btr)4]Cl2 complex adopts simpler 1D polymeric structure also incorporating trinuclear copper/chloride clusters.
Graphical abstractAn eight-connected coordination frameworks related to a CsCl (bcu) structure originate in functionality of trinuclear copper(II)/chloride ensembles bridged by 4,4′-bitriazole ligandsFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Andrey B. Lysenko, Evgen V. Govor, Konstantin V. Domasevitch,