| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310916 | Inorganica Chimica Acta | 2012 | 9 Pages |
Abstract
⺠Halide bridging Pb(II)-1-alkyl-2-(arylazo)imidazole [Pb(RaaiRâ²)(μ-X)2]n are described. ⺠The crystal structure of [Pb(MeaaiMe)(μ-Cl)2]n has confirmed bridged coordination polymer. ⺠The coordinated azoimidazole undergoes E-to-Z isomerization upon UV light irradiation. ⺠Quantum yields (ÏEâZ) of free ligand is higher than their coordinated phase in Pb(II) complex. ⺠DFT computation has explained the spectroscopic and photochromic behavior.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
D. Mallick, A. Nandi, K.K. Sarker, P. Datta, T.K. Mondal, C. Sinha,