Article ID Journal Published Year Pages File Type
1310953 Inorganica Chimica Acta 2006 5 Pages PDF
Abstract

The ferrocene-containing polymer [-fc-B(Br)-]n (6) with an average chain length of ca. 20 repeat units (n = 20) is readily accessible from fc(BBr2)2 and HSiEt3 [fc = (C5H4)2Fe] via a novel polycondensation reaction. Treatment of 6 with excess THF yields the highly soluble alkoxy-substituted derivative [-fc-B(O(CH2)4Br)-]n (10; n = 20).

Graphical abstractThe ferrocene-containing polymer [-fc-B(Br)-]n (6) with an average chain length of ca. 20 repeat units (n = 20) is readily accessible from fc(BBr2)2 and HSiEt3 [fc = (C5H4)2Fe] via a novel polycondensation reaction. Treatment of 6 with excess THF yields the highly soluble alkoxy-substituted derivative [-fc-B(O(CH2)4Br)-]n (10; n = 20).Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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