| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1310988 | Inorganica Chimica Acta | 2012 | 7 Pages |
Abstract
⺠The studies on the interaction of Cu(II) complexes containing macrotricyclic complexes with DNA are rather limited. ⺠Copper(II) complexes of 14-membered hexaaza macrocyclic ligands have been synthesized and characterized. ⺠The crystal structure of the complexes [Cu(L1)(ClO4)2] and [Cu(L2)(ClO4)2] shows a distorted octahedral geometry. ⺠The two perchlorate ions are weakly coordinated to the metal ion in the axial position. ⺠The Cu(II) complexes cleave pUC 18 DNA oxidatively in the presence of H2O2.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Subramaniam Sujatha, Sengottuvelan Balasubramanian, Babu Varghese, Mani Jayaprakashvel, Narayanasamy Mathivanan,