| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311016 | Inorganica Chimica Acta | 2005 | 6 Pages |
Abstract
The new aryl phosphinites 1 and 2 allow trans coordination in square-planar palladium(II) and rhodium(I) complexes, avoiding ortho-metallation thanks to the blocking of the ortho-positions in the O-aryl substituent.
Keywords
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![New aryl phosphinite ligands avoiding ortho-metallation: Synthesis and molecular structures of trans-[PdCl2(PPh2OR)2] and trans-[Rh(CO)Cl(PPh2OR)2] (RÂ =Â 2,4,6-Me3C6H2; 2,6-Ph2C6H3)](/preview/png/1311016.png "First Page Preview: New aryl phosphinite ligands avoiding ortho-metallation: Synthesis and molecular structures of trans-[PdCl2(PPh2OR)2] and trans-[Rh(CO)Cl(PPh2OR)2] (RÂ =Â 2,4,6-Me3C6H2; 2,6-Ph2C6H3)")
Authors
Ludovic Chahen, Lydia Karmazin-Brelot, Georg Süss-Fink,