| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311022 | Inorganica Chimica Acta | 2005 | 6 Pages |
Abstract
Dioxygenation process in the reaction of catecholatoiron(III) complexes [Fe(TPA)(Cat)]BPh4 with 18O2 was investigated by means of ESI-MS spectroscopy. The results suggest that the second oxygen atom is incorporated into muconic anhydride through the nucleophilic attack on muconic anhydride by an 18O-oxo-group of the metal center, and that this process competes with dissociation of muconic anhydride from the metal center.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Yutaka Hitomi, Masakazu Higuchi, Tsunehiro Tanaka, Takuzo Funabiki,