| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311074 | Inorganica Chimica Acta | 2011 | 7 Pages |
Abstract
⺠Phosphorylated 1,2-azaphospholanes form O-monodentate or O,O-bidentate uranium complexes. ⺠The structure of the complex depends on the difference of donor properties of the O-atoms of phosphoryl groups. ⺠In solutions monodentate complexes undergo dimerization and insertion of air oxygen affording (μ2-peroxo)-bridged complexes. ⺠The ligands bearing two asymmetric phosphorus atoms were used as individual diastereomers.
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Chemistry
Inorganic Chemistry
Authors
Inga M. Aladzheva, Olga V. Bykhovskaya, Yulia V. Nelyubina, Zinaida S. Klemenkova, Pavel V. Petrovskii, Irina L. Odinets,