| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311102 | Inorganica Chimica Acta | 2011 | 4 Pages |
Abstract
⺠Mechanism of oxidation of H2O2 and N2H5+ by [(en)(dien)CoIII(O2)CoIII(en)(dien)]5+ is discussed. ⺠The observed base catalysis in the reactions appears to be a result of an electroprotic mechanism. ⺠Acid partly consumes superoxo complex forming kinetically dead-end species, incapable to accept proton from the reductants.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sekhar Gain, Ritu Mishra, Subrata Mukhopadhyay, Rupendranath Banerjee,