| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311108 | Inorganica Chimica Acta | 2005 | 7 Pages |
Abstract
The intrinsic mechanism of two different Ir(I) cyclooctadiene complexes [Ir(LLâ²)(cod)] (LLâ²Â = 2-pyridinethiolato-N-oxide-κO-κS and N-methyl-4-methoxybenzo-thiohydroxamato-κO,κS) were investigated. High-pressure kinetics in different solvents, covering a large range of dielectric constants, was used to find a correlation between the volume of activation and the solvent properties. Volumes of activation were determined and reaction volumes calculated.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Mechanistic investigation of the oxidative addition reactions between different iridium (I) cyclooctadiene ([Ir(LLâ²)(cod)]) complexes and iodomethane](/preview/png/1311108.png "First Page Preview: Mechanistic investigation of the oxidative addition reactions between different iridium (I) cyclooctadiene ([Ir(LLâ²)(cod)]) complexes and iodomethane")
Authors
Melanie Theron, Ebeth Grobbelaar, Walter Purcell, Stephen S. Basson,