Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1311189 | Inorganica Chimica Acta | 2010 | 6 Pages |
Abstract
Density functional calculations are used to study the structure, bonding and electrochemical properties of the N2S2 nitrosyl complexes M(NO)(bme-pda) and M(NO)(bme-dach) MÂ =Â Fe, Co. Calculated structures are in good agreement with experiment. Similarity in reduction potentials for related Fe and Co complexes is explained by the formation of triplet-state reduced Fe complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
John P. Graham,