Extended structures of three new coordination polymers based on 1,10-phenanthroline derivatives and 1,4-benzenedicarboxylate mixed ligands: Preparation, structural characterization and properties

Three coordination polymers, namely, [Cd(HOIP)2(1,4-bdc)] (1), [Cu(HOIP)(1,4-bdc)] (2) and [Cu(PDIP)(1,4-bdc)] (3) (HOIP = 2-(4-hydroxylbenzene) imidazo[4,5-f]1,10-phenanthroline, PDIP = 2-(3-pyridine) imidazo[4,5-f]1,10-phenanthroline, and 1,4-bdc = 1,4-benzenedicarboxylate), have been synthesized under the hydrothermal conditions. All complexes have been characterized by elemental analyses, IR and single-crystal X-ray diffraction. Structural analyses reveal that complex 1 possesses infinite one-dimensional (1D) chain bridged by 1,4-bdc ligands, complexes 2 and 3 both exhibit two-dimensional (2D) (4,4) network structures based on dinuclear [Cu2O2] units. However, the weak interactions are different in complexes 1–3. Moreover, the thermal properties of all complexes, fluorescence property of 1, and the electrochemical behavior of 3 are also reported in this paper.

Graphical abstractThree new coordination polymers, namely, [Cd(HOIP)2(1,4-bdc)] (1), [Cu(HOIP)(1,4-bdc)] (2) and [Cu(PDIP)(1,4-bdc)] (3) have been synthesized under the hydrothermal conditions. Complex 1 possesses infinite one-dimensional chain, 2 and 3 both exhibit two-dimensional (4,4) network structures. Moreover, the fluorescence property of 1 and the electrochemical behavior of 3 are also reported.Figure optionsDownload full-size imageDownload as PowerPoint slide