Pyrazole-nitrogen bridged tetranuclear copper(II) cluster with an unprecedented U-like core: Synthesis, crystal structure and magnetic properties

Reaction of 3,5-pyrazoledicarboxylic acid with copper salt under the hydrothermal condition affords a self-assembly tetranuclear copper(II) cluster based upon mixed ligands formulated as [Cu4(μ4-Pzdc)4(Im)4]·4Dma·9H2O (1) (H3Pzdc = 3,5-pyrazoledicarboxylic acid, Im = imidazole, Dma = dimethylamine), in which the four copper(II) atoms are connected into a novel Cu4N8 metallonitrogen U-like open core through eight pyrazoledicarboxylate N atoms, and the tetranuclear clusters were further interlinked through strong hydrogen bonding interactions, resulting in three-dimensional lattice supramolecular networks. The magnetic susceptibility investigation indicates that overall weak antiferro-magnetic coupling between Cu(II) cations occurs through the pyrazole-dicarboxylate bridge (J = −13.49 cm−1).

Graphical abstractTetranuclear copper(II) cluster based upon mixed ligands has been synthesized, in which the four copper(II) atoms are connected into an unusual Cu4N8 novel metallonitrogen U-like open core through eight pyrazoledicarboxylic N atoms, and the tetranuclear motifs were connected through strong hydrogen bonding interactions to give three-dimensional lattice supramolecular frame-works.Figure optionsDownload full-size imageDownload as PowerPoint slide