| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311546 | Inorganica Chimica Acta | 2008 | 7 Pages |
Abstract
The 2S22-/S42- dichotomy in bimetallic MS4M cores having triple-decker (TD) or chair-like structures is theoretically analyzed in terms of the known experimental compounds. The extent of the disulfide coupling (or formation of a S42- ring) is on one side correlated with the electron configuration of the metals and their electronegativity, on the other side, with the physical separation between the two S2 units.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Carlo Mealli, Andrea Ienco, Abdelatif Messaoudi, Anne Poduska, Roald Hoffmann,