| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311589 | Inorganica Chimica Acta | 2008 | 6 Pages |
Abstract
Two new ruthenium methyl complexes [Li(tmed)]2[(η2,η2-nbd)RuMe4] (1) and [Li(tmed)]2[(η3,η2-C8H11)RuMe3] (2) have been made and the latter has been crystallographically characterized. Compound 2 contains a η3,η2-1,2,3:5,6-cyclooctadienyl group which arose from deprotonation of a cyclooctadiene ligand. Both complexes have been studied by 1H and 13C{1H} NMR spectroscopy.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Anionic ruthenium(II) alkyls with ancillary diene and dienyl ligands: Synthesis and structures of [(η2,η2-C7H8)RuMe4]2â and [(η3,η2-C8H11)RuMe3]2â](/preview/png/1311589.png "First Page Preview: Anionic ruthenium(II) alkyls with ancillary diene and dienyl ligands: Synthesis and structures of [(η2,η2-C7H8)RuMe4]2â and [(η3,η2-C8H11)RuMe3]2â")
Authors
Patrick M. Jeffries, Robert E. Ellenwood, Gregory S. Girolami,