| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311611 | Inorganica Chimica Acta | 2008 | 6 Pages |
Abstract
Reaction of carbon monoxide with tri-tert-butylgallium yields the dimeric tert-butylacyl complex [tBu2GaC(O)tBu]2 (1) via CO insertion into a Ga-C bond. Compound 1 has been characterized by X-ray crystallography and NMR and IR spectroscopy. Reactions of tBu3M (MÂ =Â Al, Ga) with CO are also studied by density functional theory.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mark R. Mason, Bingxu Song, Yaohua Han, Xiche Hu,