| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311637 | Inorganica Chimica Acta | 2007 | 6 Pages |
Abstract
Intervalence band properties and IR spectroelectrochemistry of the mixed-valence complexes [{Ru(tpyâ)(bpy)}2(μ-adpc)]3+ and trans,trans-[{Ru(tpyâ)(pc)}2(μ-adpc)]+ are consistent with delocalized and valence trapped mixed-valence properties respectively. Data support hole-transfer superexchange as the dominant mechanism for metal-metal coupling.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Mousa Al-Noaimi, Robert J. Crutchley,