Article ID Journal Published Year Pages File Type
1311641 Inorganica Chimica Acta 2007 7 Pages PDF
Abstract
A Pd(II) complex containing didentate triazine ligand L1 (2-(2-methylphenyl)-3-(2-pyridyl)-2,3-dihydronaphtho[2,1-e][1,2,4]triazine) [PdCl2(L1)] (1) was prepared. Complex 1 reacted with methanol in dichloromethane to yield [PdCl(L2)] (2) (L2 = N-[methoxy(2-pyridyl)methyl]-1-(2-methylphenylazo)-2-naphthylamide). The structures of these complexes were determined by X-ray crystallography. A reversible ring opening and closure reaction of the triazine ligand was observed. Equilibria and kinetics of the reaction were investigated.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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