Photophysical characterization of methyl viologen ion-exchanged within a zirconium phosphate framework

The photophysical properties of 1,1′-dimethyl-4,4′dipyridinium (methyl viologen, MV2+) intercalated within zirconium phosphate (ZrP) were investigated. The intercalation of MV2+ within ZrP was achieved by ion-exchange using a hydrated form of ZrP with six water molecules per formula unit and an interlayer distance of 10.3 Å. The intercalation yields a new phase with an interlayer distance up to 10.6 Å. The MV2+-exchanged ZrP material was characterized using elemental analysis, XRPD and IR data. The MV2+-exchanged ZrP materials show a red shift in the UV–Vis spectra in contrast with solution. The photoexcitation of nitrogen purged, MV2+-exchanged ZrP water suspensions with UV light leads to fluorescence emission with a maximum at 337 nm. The photoexcitation of MV2+-exchanged ZrP suspensions without nitrogen purging yields two fluorescence emissions with maxima at 337 and 450 nm. The emission in the visible region can be attributed to a photodecomposition product. The fluorescence quantum yields indicate that the emission of MV2+-exchanged ZrP is of the same order of magnitude as that of MV2+ in water indicating a strong deactivation of the excited state by non-radiative pathways.

Graphical abstract1,1′-Dimethyl-4,4′ dipyridinium (methyl viologen, MV2+) has been intercalated within layered zirconium phosphate (ZrP) producing a new phase with an interlayer distance of 10.6 Å. MV2+-exchanged ZrP is fluorescent and the presence of oxygen promotes emission from photodecomposition products.Figure optionsDownload full-size imageDownload as PowerPoint slide