Article ID Journal Published Year Pages File Type
1311712 Inorganica Chimica Acta 2006 6 Pages PDF
Abstract
Quadruple Me2biim-bridged di- and tetranuclear complexes [Cu2(H2O)2(Me2biim)4](SO4)2 (1) and [Cr4(μ-Cl)(μ-Me2biim)8(H2O)2](ClO4)7 (2) have been prepared and characterized. The repulsion between the methyl groups forces the two imidazole rings out of coplanarity, responsible for the much weaker magnetic exchange coupling between the Cu2+ ions in 1.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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