Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1311759 | Inorganica Chimica Acta | 2006 | 9 Pages |
Abstract
Three new homopolynuclear complexes with azido bridges have been obtained by using [Cu(AA)(BB)]+ building-blocks (AA = acetylacetonate; BB = 1,10-phenanthroline or 2,2â²-bipyridine): [{Cu(acac)(phen)}2(μ1,3-N3)](ClO4) · 2H2O (1), [{Cu(acac)(phen)(ClO4)}2{Cu(phen)(μ1,1-N3)2}2] (2), [{Cu(acac)(bipy)}2(μ1,3-N3)]3(ClO4)3 · 3.75H2O (3). The cryomagnetic investigation of the tetranuclear complex, 2, reveals ferromagnetic interactions between the copper ions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Augustin M. Madalan, Mathias Noltemeyer, Mirela Neculai, Herbert W. Roesky, Marc Schmidtmann, Achim Müller, Yves Journaux, Marius Andruh,