Coordination polymers built from Cu(II) and pyrazine-2,3,5,6-tetracarboxylate or pyridine-2,4,6-tricarboxylate: Structural and magnetic studies

Room temperature reaction of Cu(NO3)2 · 6H2O and pyrazine-2,3,5,6-tetracarboxylic acid (ptecH4) in the presence of pyridine (py) in water–methanol (1:1) mixture results in the formation of {[Cu2(ptec) · (py)2 · (H2O)3] · 4H2O}n (1). With pyridine-2,4,6-tricarboxylic acid (pytcH3) and Cu(NO3)2 · 6H2O, crystals of {[Cu(pytc)] · 1/2[Cu(H2O)6] · H2O}n (2) could be obtained hydrothermally at 180 °C. The structure of 1 consists of 2D polymeric sheets. These sheets are stacked on top of one another due to strong C–H⋯π interactions forming an overall 3D structure. The structure of 2, on the other hand, consists of twin-chain coordination polymers. The void spaces between two polymeric chains are occupied by [Cu(H2O)6]2+ ions which are H-bonded to the polymeric chains. The variable temperature magnetic measurements for 1 and 2 show weak antiferromagnetic interaction between Cu(II) centers. The EPR spectra of the compounds are consistent with their structures.

Graphical abstractReaction of Cu(NO3)2 · 6H2O and pyrazine-2,3,5,6-tetracarboxylic acid in the presence of pyridine at room temperature gives a 2D net which form a 3D structure via C–H⋯π interactions. With pyridine-2,4,6-tricarboxylic acid, the metal salt forms a 2D structure, which is assembled by Cu(H2O)6 to a 3D structure.Figure optionsDownload full-size imageDownload as PowerPoint slide