Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1311772 | Inorganica Chimica Acta | 2006 | 7 Pages |
Abstract
Bi-nuclear neutral sulfur-nitrosyl iron complex has centrosymmetrical dimeric structure, with the iron atoms being linked via μ-N-C-S bridge, δFe is 0.180(1) mm/s and ÎEQ is 0.928(2) mm/s at T = 290 K. By comparative studying the mass-spectra in the gaseous phase of solid samples decomposition and kinetics of NO release in 1% aqueous solutions of dimethylsulfoxide, using of the ligand with CH3 substituent in position 1 of imidazole-2-thiol was shown to yield a more stable donor of nitrogen monoxide than earlier obtained analog with imidazole-2-thiol.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
N.A. Sanina, T.N. Rudneva, S.M. Aldoshin, G.V. Shilov, D.V. Kortchagin, Yu.M. Shul'ga, V.M. Martynenko, N.S. Ovanesyan,