| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1311806 | Inorganica Chimica Acta | 2005 | 7 Pages |
Abstract
The 'basic trinuclear iron(III) acetate' ion aquates via two proton assisted rate determining steps to produce an unstable intermediate, which contains dangling acetate ligands. This intermediate aquates rapidly and completely to aqueous iron(III) and acetate in perchloric acid media.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Paul T. Maragh, Sonia E. Thomas, Tara P. Dasgupta,
![First Page Preview: Kinetics and mechanism of the aquation of the trinuclear cation, [μ3-oxo-triaqua-hexakis(acetato)tris(iron(III))]+in perchloric acid media Kinetics and mechanism of the aquation of the trinuclear cation, [μ3-oxo-triaqua-hexakis(acetato)tris(iron(III))]+in perchloric acid media](/preview/png/1311806.png)