Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1311831 | Inorganica Chimica Acta | 2005 | 8 Pages |
Two salts consisting of ammonium-crown ether supramolecular cation with bis(maleonitriledithiolato)copperate (II), (NH4)2(15-crown-5)3[Cu(mnt)2] (1) and (NH4)2(benzo-15-crown-5)4[Cu(mnt)2] · 0.5H2O (2), have been synthesized and structurally characterized. The distinct structures of supramolecular cation, an unusual triple-decker dication in 1 and a sandwich dimer in 2, were observed. X-band EPR studies on the single crystals of both 1 and 2 have been carried out at room temperature, which revealed that 1 possesses a single resonance line whereas 2 shows a perfect hyperfine structure. The spin-density distribution in the anionic moiety of 2 is calculated on DFT method and compared well with the experimental data.
Graphical abstractThe crystal structures, magnetic susceptibilities and single-crystal X-band EPR studies on two salts consisting of ammonium-crown ether supramolecular cation with bis(maleonitriledithiolato)copperate (II), (NH4)2(15-crown-5)3[Cu(mnt)2] (1) and (NH4)2(benzo-15-crown-5)4[Cu(mnt)2] · 0.5H2O (2) have been reported. The spin-density distribution in the anionic moiety of 2 are calculated by DFT method and compared with the experimental data.Figure optionsDownload full-size imageDownload as PowerPoint slide