| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1312046 | Inorganica Chimica Acta | 2016 | 5 Pages |
•A phenoxo-O bridged compound, [Dy2(dbm)4(L)2]2 (1), have been synthesized and structurally characterized.•Magnetic measurements indicated that slow relaxation of the magnetization was clearly observed in 1, typical of SMM behavior.•The dinuclear dysprosium compound 1 possesses excellent solvent stabilities.
A dinuclear dysprosium compound, [Dy2(dbm)4L2]2(1) (Hdbm = 1,3-diphenyl-1,3-propanedione, HL = 2-[[(4-fluorophenyl)imino]methyl]-8-hydroxyquinoline), have been synthesized, structurally and magnetically characterized. The X-ray structural analysis exhibits that the compound 1 is phenoxo-O bridged binuclear compound, in which two DyIII ions are bridged by two phenoxido oxygen atoms of two 8-hydroxyquinoline Schiff base ligands. Each DyIII centers exhibit an eight-coordinated environment. Magnetic measurements indicated that slow relaxation of the magnetization was clearly observed in 1, typical of SMM behavior.
Graphical abstractA dinuclear dysprosium compound, [Dy2(dbm)4(L)2]2 (1) (dbm = 1,3-diphenyl-1,3-propanedione, L = 2-[[(4-fluorophenyl)imino]methyl]-8-hydroxyquinoline), have been synthesized, structurally and magnetically characterized. Magnetic measurements indicated that slow relaxation of the magnetization was clearly observed in 1, typical of SMM behavior.Figure optionsDownload full-size imageDownload as PowerPoint slide
