| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1312193 | Inorganica Chimica Acta | 2014 | 8 Pages |
•Porphyrins and Zn-porphyrins with different pending arms have been synthesized.•Their photophysical properties are modulated by the substituents.•Molecular recognition experiments have been performed.•Zn-porphyrins are able to recognize no-bulky amines.
Two new porphyrins and their zinc(II) complexes have been synthesized, their photophysical properties studied, and their use in the molecular recognition of amines has been analyzed. The luminescence properties of both series of compounds show a decrease on the luminescence quantum yield of the Zn-derivatives with respect to their corresponding free base porphyrins. Attempts to probe the ability of the compounds to recognise certain biologically relevant drugs revealed that dimethylformamide (DMF) is capable of binding the zinc(II) porphyins. This fact led us to perform sensing experiments of different aliphatic amines, the highest calculated association constant for methyl- and trimethylamine. These properties confirm the sensitivity of porphyrins to the binding of closely related analytes.
Graphical abstractTwo new porphyrins and their zinc(II) complexes have been synthesized, their photophysical properties studied, and their use in the molecular recognition of amines has been analyzed.Figure optionsDownload full-size imageDownload as PowerPoint slide
