| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1312468 | Inorganica Chimica Acta | 2012 | 5 Pages |
Abstract
⺠NMe4[N2B10H9] reacts with diamino ligands L at 120 °C after 15 h under argon. ⺠When L is flexible, the reaction yielded the monocage NMe4[B10H9L]. ⺠When LⲠis a good nucleophile and not flexible, formation of dicages is observed. ⺠Chelating atoms of LⲠshould not hinder each other upon binding to the boron cages. ⺠Some LⲠhinders the formation of dicages due to steric and electronic effects.
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Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![The reaction of closo-diazononahydrodecaborate [1-N2B10H9]â with bidentate diamino ligands L: A new route to dicage derivatives [B10H9LB10H9]2â](/preview/png/1312468.png "First Page Preview: The reaction of closo-diazononahydrodecaborate [1-N2B10H9]â with bidentate diamino ligands L: A new route to dicage derivatives [B10H9LB10H9]2â")
Authors
Daoud Naoufal, Zeina Assi, Enaya Abdelhai, Ghassan Ibrahim, Ogaritte Yazbeck, Ali Hachem, Hassan Abdallah, Mirvat El Masri,