| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1312585 | Inorganica Chimica Acta | 2010 | 5 Pages |
Abstract
The novel bimetallic alkylidene complexes of molybdenum (RF3O)2(ArN)MoCH-SiMe2-CHMo(NAr)(ORF3)2 (1) and (RF3O)2(ArN)MoCH-SiPhVin-CHMo(NAr)(ORF3)2 (2) (Ar = 2,6-Pri2C6H3; RF3 = CMe2CF3) were synthesized and structurally characterized. The compounds 1 and 2 were found to initiate ROMP of cyclooctene and led to the formation of high molecular weight polyoctenamers with predominant trans-units content in the case of 1 and predominant cis-units content in the case of 2.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Synthesis and structures of bimetallic silicon-containing imido alkylidene complexes of molybdenum Me2Si[CHMo(NAr)(ORF3)2]2 and PhVinSi[CHMo(NAr)(ORF3)2]2](/preview/png/1312585.png "First Page Preview: Synthesis and structures of bimetallic silicon-containing imido alkylidene complexes of molybdenum Me2Si[CHMo(NAr)(ORF3)2]2 and PhVinSi[CHMo(NAr)(ORF3)2]2")
Authors
Yulya P. Barinova, Yulya E. Begantsova, Natalia E. Stolyarova, Irina K. Grigorieva, Anton V. Cherkasov, Georgii K. Fukin, Yurii A. Kurskii, Leonid N. Bochkarev, Gleb A. Abakumov,