Article ID Journal Published Year Pages File Type
1312620 Inorganica Chimica Acta 2010 8 Pages PDF
Abstract
The reaction of Ph2PCH2CH2PPh2 with BrCH2C(O)C6H4NO2 affords a mixture of both the mono- and diphosphonium salt simultaneously. The reaction of mercury(II) halides with [Ph2PCH2CH2PPh2CHC(O)C6H4NO2] yielded P,P-coordinated complexes. The result of theoretical study showed that the experimentally determined structure of the complex {HgI2(Ph2PCH2CH2PPh2CHC(O)C6H4NO2)2} (7) is more stable than its potential geometrical isomers.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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