Electrochemical synthesis and crystal structure of iron(II), cobalt(II), nickel(II) and copper(II) complexes of dianionic tetradentate N4 Schiff base ligand

The electrochemical oxidation of anodic metal (iron, cobalt, nickel and copper) in an acetonitrile solution of the potentially chelating Schiff base N,N(dithiodiethylenebis-(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide (H2L) afforded stable complexes of empirical formula [ML]. The compounds obtained have been characterized by microanalysis, IR spectroscopy and ES-MS mass spectrometry. The crystal and molecular structures of [FeL]·CH3CN (1) [CoL]·CH3CN (2), [NiL]·CH3CN (3) and [CuL]·CH3CN (4) have been determined by X-ray diffraction in all complexes, the metal atom is in a distorted tetrahedral environment with the Schiff base acting as a tetradentate N4 donor.

Graphical abstractHerein we report the coordination chemistry of iron, cobalt, nickel and copper with the potentially tetradentate dianionic Schiff base, N,N(dithiodiethylenebis-(aminylydenemethylydene)-bis(1,2-phenylene)ditosylamide. The crystal and molecular structures of [FeL]·CH3CN (1) [CoL]·CH3CN (2), [NiL]·CH3CN (3) and [CuL]·CH3CN (4) have been determined by X-ray diffraction. In all complexes the metal atom is in a distorted tetrahedral environment with the Schiff base acting as a tetradentate N4 donor.Figure optionsDownload full-size imageDownload as PowerPoint slide