Article ID Journal Published Year Pages File Type
1312629 Inorganica Chimica Acta 2010 5 Pages PDF
Abstract
The reaction of 3-mercaptophenol with diphenylchlorophosphine in a 1:2 ratio in the presence of NEt3 as base, affords cleanly the non-symmetric ligand [C6H4-1-(SPPh2)-3-(OPPh2)] (1). The direct reaction of this ligand with PdCl2 in toluene (reflux) affords the non-symmetric phosphinito-thiophosphinito PSCOP pincer complex [PdCl{C6H3-2-(SPPh2)-6-(OPPh2)}] (2).
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Authors
, , ,