Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312629 | Inorganica Chimica Acta | 2010 | 5 Pages |
Abstract
The reaction of 3-mercaptophenol with diphenylchlorophosphine in a 1:2 ratio in the presence of NEt3 as base, affords cleanly the non-symmetric ligand [C6H4-1-(SPPh2)-3-(OPPh2)] (1). The direct reaction of this ligand with PdCl2 in toluene (reflux) affords the non-symmetric phosphinito-thiophosphinito PSCOP pincer complex [PdCl{C6H3-2-(SPPh2)-6-(OPPh2)}] (2).
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Juan M. Serrano-Becerra, Simón Hernández-Ortega, David Morales-Morales,