Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312646 | Inorganica Chimica Acta | 2010 | 6 Pages |
Abstract
Two unusual lithium coordinated binuclear platinum- and rhodium-hydride complexes [M(dippe)(H)]2·LiHBEt3 were synthesized and characterized by NMR spectroscopy and X-ray crystallography. Not only does the lithium ion interact with the metal hydrides, but also with the B–H bond of the borohydride.
Graphical abstractAn unusual binuclear platinum-hydride complex [Pt(dippe)(H)]2.LiHBEt3 shows a lithium ion bridging the two platinum hydrides and coordinating to the hydride of the HBEt3 unit. A related compound, [Rh(dippe)]2(μ-H)2·LiHBEt3], has also been prepared and structurally characterized, but now shows bridging hydrides coordinated to the LiHBEt3 moiety.Figure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Brett D. Swartz, Tülay A. Ateşin, Matthew R. Grochowski, Stephen S. Oster, William W. Brennessel, William D. Jones,