Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312647 | Inorganica Chimica Acta | 2010 | 10 Pages |
Abstract
The addition of small amounts of hydrido-carbonyl rhenates or simply of Hâ to the “ethylene-like” complex [Re2(μ-H)2(CO)8] triggers an oligomerization process, that affords hydrogen-rich chain clusters made of Re(CO)4 units joined by Re(μ-H)Re interactions. Each oligomerization step is reversible, and the equilibria favour the longer oligomers at the lowest temperatures, where nuclearities up to 10 are reached.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Daniela Maggioni, Tiziana Beringhelli, Giuseppe D'Alfonso, Daniela Donghi, Monica Panigati,