Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312836 | Inorganica Chimica Acta | 2006 | 4 Pages |
Abstract
Deprotonated 1,3-bis(4-nitrophenyl)triazene reacts with TlNO3 to give {[TlI(RC6H4NNNC6H4R)]2}n [R = p-NO2], the first triazenide complex polymer of TlI. The centrosymmetric tectons [TlI(RC6H4NNNC6H4R)]2 attain unidimensional chains through Tlâ¯O bonding. Weak secondary Ï-interactions of the type Tl-η2-arene between the unidimensional chains complete the supramolecular bidimensional assembling of the lattice.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Manfredo Hörner, Gelson Manzoni de Oliveira, Leandro Bresolin, Adriano Bof de Oliveira,