Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1312843 | Inorganica Chimica Acta | 2006 | 5 Pages |
Abstract
3-(4-Phenyldiazophenyl)-1-(4-nitrophenyl)triazenide reacts with Hg(CH3COO)2 and pyridine to give {[HgII(Py)2(PhN2C6H4NNNC6H4R)2]2}n (Py = pyridine; R = NO2), the first reported HgII-Py complex with two coordinating pyridine molecules. The tectons [HgII(Py)2(PhN2C6H4NNNC6H4R)2] are linked to pairs as centrosymmetric dimers through reciprocal metal-η2-arene Ï-interactions. The dimers are assembled by translation on the ac plane to unidimensional chains linked through non classical C-Hâ¯O hydrogen bonds.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Manfredo Hörner, Gelson Manzoni de Oliveira, Lorenzo do Canto Visentin, Renato Silveira Cezar,